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Re: FUELCAT - FACT OR FICTION ?

To: elliottd <elliottd@look.ca>
Subject: Re: FUELCAT - FACT OR FICTION ?
From: "Michael D. Porter" <mporter@zianet.com>
Date: Thu, 27 Nov 2003 18:02:13 -0700
elliottd wrote:

> SOUNDS TOO GOOD TO BE TRUE ?  Any Comments ?
> 
> http://www.carburetters.co.uk/Fuelcat.php#Information

It's hard to say. I'll try, to the extent I know of catalysis, to offer this 
possible explanation. We know that 
catalysis is a known phenomenon in chemistry. It does work, and even catalysis 
specialists often cannot define the exact 
process (see a few of the papers by a guy named Sinfeld). In fact, catalysis is 
commonly used at the inlet side of the 
fuel system--at the refinery. There, it's a messy process and the catalysts 
have to be refreshed frequently, and other 
separation functions are handled by distillation columns.

Gasoline, however, is pretty much a soup of hydrocarbons. Benzene (although 
used now in much less concentration than in 
the past, for health reasons), toluene, C4 through C12 branched paraffins, 
cyclohexanes, xylene, all are part of what we 
call gasoline. The formulation can vary by region and climate, but those 
formulation differences are relatively small 
changes in volatiles (lighter volatiles for use in colder weather, etc.).

It's also fairly well-known that the greater the number of carbon-carbon bonds 
to be broken in the fuel, the more likely 
there will be deposition of free carbon. So, if there were a catalytic process 
that could reform some of the 
lower-volatile, higher carbon compounds into higher volatile, lower carbon 
compounds, then there might some benefit for 
lower carbon deposition.

As for octane improvement, there is a catalytic process which will reform 
methylcyclohexane into toluene (toluene having 
an octane rating of about 118). Chromium and similar metals are used in the 
production of iso-butane. Platinum-tin and 
tin-silicon dioxide alloys have been used in hydrocarbon reforming for some 
time, I believe. That said, invariably, fuel 
value of higher octane components is lower, so there would have to be some 
other great improvement in combustion 
efficiency to offset the loss of fuel value.

As for valve recession, it may not be a matter so much of combustion temps, but 
if there's a reforming of some 
hydrocarbons through catalysis, this may change the types of organic acids 
formed upon combustion, so valve and seat 
erosion may be partly dependent upon the acid concentrations and their types. 
In the past, lead deposits on the valves 
and seats might have provided a sort of ablative surface which was constantly 
replenished by lead in the fuel, so there 
was less erosion of the metal parts by acids.

As far as this particular product goes, the magnets in the in-line fuel 
container are of very dubious value, but there 
is some chemical literature on the use of tin alloys as catalysts. Without 
knowing the composition of the catalyst, 
however, one probably can't make sense of the catalysis occurring, if any, or 
how rate-dependent is the catalysis. The 
only other ways I can think of to determine the efficacy of the device would be 
to add the catalyst to a fuel of known 
composition and then fractionate the resultant through distillation and see if 
there is any reforming going on, or 
perhaps compare the resultant to the known fuel with something like atomic 
absorption. Or just put the resultant through 
a standard octane test engine.

It's interesting, though, that most of the mention of the Broquet catalyst in a 
Google search (regardless of product 
name) is from other parts of the world, rather than the US. Whether that's a 
function of general indifference in the US 
toward fuel efficiency due to low fuel prices, or a matter of US consumer 
protection law, I couldn't say.

Might make for an interesting Google search to see if any of the trade names 
for this catalyst are mentioned in 
government consumer fraud suits. What I see in a lot of the consumer 
testimonials is familiar--general belief in the 
efficacy of the product, but are very short on real test data. Someone with 
money to burn on a chassis dyno could 
probably determine if it helps or not.

Cheers.

-- 
Michael D. Porter
Roswell, NM
[mailto:mporter@zianet.com]

Never let anyone drive you crazy when you know it's within walking distance.

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